Product ID:PIC REAGENT A LOW UV, 84189
MSDS Date:11/16/1994
FSC:6630
NIIN:00N072645
MSDS Number: CDWTJ

WATERS CORP

34 MAPLE ST
MILFORD, MA 01757
US

Emergency Phone: 615-366-2000

Info Phone: 508-478-2000

Cage: 00W06

WATERS CORP

MILFORD, MA 01757 US

Telephone: 508-478-2000

Cage: 00W06

TETRABUTYLAMMONIUM PHOSPHATE

CAS: 5574-97-0

Fraction By Weight: 20-25%

OSHA PEL N/K

ACGIH TLV: N/K

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA).

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 20-25%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 50%

OSHA PEL N/K

ACGIH TLV: N/K

AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS.

RTECS: 9999999ZZ

DEVICE/ANY DISCOLORATION OF TANK DUE TO FIRE. ISOLATE

RTECS: 9999999ZZ

TRUCK IS INVOLVED IN FIRE. EXTING ONLY IF FLOW CAN BE

RTECS: 9999999ZZ

STREAMS MAY BE INEFT. COOL CNTNRS W/FLOODING AMTS OF

RTECS: 9999999ZZ

KEEP UPWIND.

RTECS: 9999999ZZ

VERTIGO/DIZZ, NAUS, VOMIT, OCCAS DIARR,

RTECS: 9999999ZZ

RESTLESSNESS, APATHY/DELIRIUM, EXCITEMENT & MANIA.

RTECS: 9999999ZZ

CLAMMY SKIN, HYPOTENSION, CYANOSIS, OPISTHOTONOS,

RTECS: 9999999ZZ

NEURITIS, CEREBRAL & PULM EDEMA, UNCON & COMA. EFTS

RTECS: 9999999ZZ

DILATED, UNRESPONSIVE PUPILS, PTOSIS, PAIN,

RTECS: 9999999ZZ

COLOR PERCEPTION, PHOTOPHOBIA & OPTIC NERVE ATROPHY.

RTECS: 9999999ZZ

DEAFNESS. LIVER, KIDNEY, HEART, STOMACH, INTEST &

RTECS: 9999999ZZ

NERV SYS INCL DFCLTY IN SPEECH, MOTOR DYSFUNC

RTECS: 9999999ZZ

EFTS AS IN ACUTE INGEST. RECURRENT HDCHS IN WORKERS.

RTECS: 9999999ZZ

DEFAT RSLTG

RTECS: 9999999ZZ

CHRONIC ABSORPTION MAY OCCUR & CAUSE METABOLIC

RTECS: 9999999ZZ

VISUAL IMPAIRMENT,

RTECS: 9999999ZZ

CNS DEPRESSANT; NEUROTOXIN. FOR

RTECS: 9999999ZZ

LATER DISP. NO SMOKING, FLAMES/FLARES IN HAZ

RTECS: 9999999ZZ

ENTRY. FOR MORE SPECIFIC INFORMATION CONTACT NEHC .

RTECS: 9999999ZZ

BY ELECTROSTATIC SPKS, SHOULD BE STORED IN

RTECS: 9999999ZZ

SPECIFIED IN NFPA 77-1983, RECOMMENDED PRACTICE ON

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 2.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:ING 2:NARC/NEUROTOXIN.
IRRIT OF MUC MEMBS, COUGH, OPPRESSION IN CHEST, TRACHEITIS, BRONCH,
TINNITUS, UNSTEADY GAIT, TWITCHING, COLIC, CONSTIP, NYSTAGMUS,
BLEPHAROSPASM, PARESTHESIAS, NUMB, SHOOTING PAINS IN HANDS &
FOREARMS, METABOLIC ACIDOSIS & EFTS ON EYES & CNS AS IN ACUTE
INGEST. SKIN: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ING 1:IRRIT. ING 2:NARC/NEUROTOX.
IRRIT. EYE:ING 1:IRRIT. ING 2:IRRIT. VIOLENT INFLAMM OF CONJ &
EPITHELIAL DEFECTS ON CORNEA. INGEST:ING 1:HARMFUL. ING
2:NARC/NEUROTOXIN. MILD & TRANSIENT IN EBRIATION & SUBSEQUENT DROW
FOLLOWED BYASYMPTOMATIC PERIOD. FOLLOWING DELAY-COUGH, DYSP, HDCH,
DULL, WEAK, (ING 9)
Medical Cond Aggravated by Exposure:PERSONS W/KIDNEY, EYE OR SKIN
DISORDERS ARE AT INCREASED RISK FROM EXPOSURE.

First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM
MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . FOR MORE
SPECIFIC INFORMATION REGARDING FIRST AID TREATMENT CONTACT NEHC .

Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER
SPRAY/ALCOHOL-RESIST FOAM. FOR LARGER FIRES, USE WATER
SPRAY/ALCOHOL-RESIST FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNR FROM AREA IF YOU CAN DO IT W/OUT RISK. DIKE FIRE-CONTROL
WATER FOR LATER DISP; DO NOT SCATTER(SUPDAT)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME. VAPS ARE HVR/AIR & MAY TRAVEL CONSIDERABLE DIST TO A
SOURCE OF IGNIT & FLASH BACK. VAP-AIR MIXTS ARE EXPLO.

Spill Release Procedures:SHUT OFF IGNIT SOURCES. DO NOT TOUCH SPILLED
MATL. STOP LEAK IF YOU CAN DO IT W/OUT RISK. USE WATER SPRAY TO
REDUCE VAPS. SM SPILLS:TAKE UP W/SAND OR OTHER ABSORB MATL & PLACE
INTO CNTNRS FOR LATER DI SP. LG SPILLS:DIKE FAR AHEAD OF SPILL FOR
(ING 22)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OBSERVE ALL FED, STATE & LOC REGS WHEN
STORING THIS SUBSTANCE. STORE I/A/W 29 CFR 1910.106. STORE AWAY
FROM INCOMPAT SUBSTANCES. FLAMM LIQ & VAP.
Other Precautions:MAY CAUSE FLASH FIRE. KEEP AWAY FROM ALL IGNIT
SOURCES. AVOID BRTHG VAP/MIST. AVOID CONT W/EYES, SKIN & CLTHG.
KEEP CNTNR TIGHTLY CLSD. USE ONLY W/ADEQ VENT. HANDLE W/CAUT.
SUBSTANCES W/LOW ELECTROCON DUCTIVITY, WHICH MAY BE IGNITED (ING
24)

Respiratory Protection:SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM
LEVELS FOUND IN WORK PLACE, SPECIFIC OPERATION, MUST NOT EXCEED
WORKING LIMS OF RESP & MUST BE NIOSH APPRVD: ANY TYPE 'C'
SUPPLIED-AIR RESP W/FULL FACEPI ECE OPERATED IN PRESS-DEMAND/
(SUPDAT)
Ventilation:PROVIDE LOC EXHST VENT TO MEET PELS. VENT EQUIP SHOULD BE
EXPLO-PROOF IF EXPLO CONCS OF DUST, VAPOR OR FUME ARE PRESENT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING & EQUIPMENT.
Work Hygienic Practices:WASH THORO AFTER HNDLG. ANY CLTHG WET W/FLAMM
LIQ SHOULD BE IMMED REMOVED AT LOCATION WHERE IT IS WETTED TO
(SUPDAT)
Supplemental Safety and Health
RESP PROT:OTHER POS PRESS MODE OR W/FULL FACEPIECE, HELMET/HOOD
OPERATED IN CONTINUOUS-FLOW MODE; ANY SCBA W/FULL FACEPIECE
OPERATED IN PRESS-DEMAND/OTHER POS PRESS MODE. HYGIENE PRACT:PVNT
BURNS FROM POSS IGNIT. FIRE FIGHT PROC:MATL. APPLY COOLING WATER
TO SIDES OF CNTNRS THAT ARE EXPOS TO FLAMES UNTIL WELL (ING 4)

Vapor Pres:24 @ 25C
Vapor Density:0.7
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ALUMINUM, CHLORINE, METALS, NICKEL. FOR A COMPLETE
LISTING OF MATLS TO AVOID CONTACT NEHC .
Stability Condition to Avoid:NO DATA AVAILABLE.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC &/OR HAZARDOUS GASES.

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE. DISPOSAL MUST BE I/A/W STANDARDS
APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA
HAZARDOUS WASTE NUMBER D0 01. RQ:100 LBS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.